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| You are here :everlast4steel.com ---> Safety ---> M.S.D.S. Part B |
11/28/08
MATERIAL SAFETY DATA SHEET Page 01 of 07
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| M A T E R I A L S A F E T Y D A T A S H E E T |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : EVERLAST® C.A.R.O.L. PART B
IDENTIFICATION NUMBER: 35671, 35672, 35673
PRODUCT USE/CLASS : Anti Rust Primer
MANUFACTURER:
MADE IN EU by POLYOXETANE LTD
London W2 2AP, United Kingdom
EU and WORLDWIDE 24 hr emergency contact :
Paul Bruns GmbH, Hamburg Germany
Phone +49 40 54 77 850
Fax +49 40 54 77 8520
PREPARER: Safety Health & Regulatory Affairs PREPARE DATE: 11/28/08 update 2009
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 Acetic acid, 3-methoxybutyl ester 4435-53-4 20.0
02 Diphenylmethane Diisocyanate (2,2;2,4) 26447-40-5 5.0-10.0
03 4,4'-diphenylmethanediisocyanate 101-68-8 5.0-10.0
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 50 mg/m3 100 mg/m3 50 mg/m3 N/E N.E. NO
03+02 .005ppm N.E. N/A 0.02ppm N.E. NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: May cause target organ or system damage. Refer to
chronic health effects section. Causes skin and eye irritation. May cause
allergic skin reaction.
POLYOXETANE LTD 11/28/08
MATERIAL SAFETY DATA SHEET Page 02 of 07
Item No.: 35672
ACUTE EFFECTS - EYE CONTACT: Contact may cause injury to eye tissue if not
removed promptly.
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| SECTION 3 - HAZARDS IDENTIFICATION |
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ACUTE EFFECTS - SKIN CONTACT: May be absorbed through the skin in harmful
amounts. Repeated or prolonged contact may cause sensitization. Moderate
irritant. Prolonged contact may cause dermatitis.
ACUTE EFFECTS - INHALATION: Vapors and/or aerosols which may be formed at
elevated temperatures may be irritating. Strong respiratory sensitizer.
ACUTE EFFECTS - INGESTION: Moderately toxic. May cause irritation or
burns of mouth, throat, and stomach, with nausea, abdominal pain, and
possible collapse. Ingestion may cause fatigue, muscular weakness, labored
breathing. Ingestion of significant amounts may cause kidney damage.
CHRONIC OVEREXPOSURE EFFECTS: N.A.
OTHER INFORMATION: Not Applicable.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush eyes with plenty of water for at least 15
minutes. Get immediate medical attention.
SKIN CONTACT: Remove contaminated clothing. Wash skin with soap and
water. Get medical attention.
INHALATION: If symptoms occur, remove to fresh air. Medical personnel may
administer oxygen if breathing is difficult. Seek medical attention if
symptoms persist.
INGESTION: Swallowing less than an ounce will not cause significant harm.
POLYOXETANE LTD 11/28/08
MATERIAL SAFETY DATA SHEET Page 03 of 07
Item No.: 35672
For larger amounts, DO NOT induce vomiting, but give one or two glasses of
water to drink and get medical attention.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 61 Celsius 142 F LOWER EXPLOSIVE LIMIT: 0.8 Vol%
(PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: 4.7 Vol%
AUTOIGNITION TEMPERATURE: 410 Celsius 770 F
EXTINGUISHING MEDIA: ALCOHOL FOAM, CO2, DRY CHEMICAL, FOAM, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may rupture or
explode (due to pressure build-up) when exposed to extreme heat.
Irritating and/or toxic gases or fumes may be generated by thermal
decomposition or combustion.
SPECIAL FIREFIGHTING PROCEDURES: Use NIOSH-approved self-contained
breathing apparatus and full protective clothing. Use water to cool
exposed containers. Water stream directed into fire may cause frothing
with subsequent spread of flame.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Reclaim clean
material. Wear appropriate protective equipment during cleanup. Absorb
with inert material, such as clay. Pick up and place in loosely-covered
waste container. Dispose of in accordance with federal, state, and local
regulations. Decontaminate or dispose of contaminated clothing and
articles. Rinse floor with mild detergent solution, letting the solution
remain on the contaminated area for at least 15 minutes before removal.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Follow all MSDS/label precautions even after container is
emptied because it may retain product residues. Avoid contact with skin
and eyes. FOR INDUSTRIAL USE ONLY.
STORAGE: KEEP OUT OF THE REACH OF CHILDREN.
POLYOXETANE LTD 11/28/08
MATERIAL SAFETY DATA SHEET Page 04 of 07
Item No.: 35672
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: General ventilation usually adequate. Local exhaust
as needed to control vapor or dust levels to below lowest component TLV.
RESPIRATORY PROTECTION: None normally required under general ventilation.
If TLV/PEL is exceeded, if use is performed in a poorly-ventilated space,
or if inhalation effects occur, use NIOSH-approved vapor cartridge
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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respirator in accordance with applicable health and safety regulations and
manufacturer's recommendations.
SKIN PROTECTION: Clean clothing to cover skin. Saranex gloves. Butyl
rubber gloves. Neoprene gloves. Nitrile gloves. PVA gloves.
EYE PROTECTION: Chemical splash goggles.
OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. Do not smoke or eat during use. DO NOT reuse empty containers
without commercial clean or recondition. Follow all MSDS/label precautions
even after container is emptied.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 173 -175 Celsius VAPOR DENSITY : Is heavier than air
ODOR : Mild ester ODOR THRESHOLD : No data
APPEARANCE : Brown to amber EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Negligible/reacts Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 1.160
VAPOR PRESSURE : No data pH @ 0.0 % : N/A
PHYSICAL STATE : Liquid VISCOSITY : Low
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Exposure to moisture.
INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants.
Reaction with amines and mercaptans in large amounts or under uncontrolled
conditions releases considerable heat and may release acrid fumes. Water.
Alcohols.
POLYOXETANE LTD 11/28/08
MATERIAL SAFETY DATA SHEET Page 05 of 07
Item No.: 35672
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Oxides of nitrogen,
ammonia. Toxic monomers. Various hydrocarbons. Irritating aldehydes and
ketones. Traces of hydrogen cyanide in oxygen-deficient environments.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Diphenylmethane Diisocyanate (2,2;2,4 Not Applicable Not Applicable
4,4'-diphenylmethanediisocyanate Not Applicable
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: Not Applicable.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: Review all current federal, state, and local regulations
regarding health and disposal for appropriate disposal procedures.
Not RCRA regulated. Cured product is inert and non-hazardous.
Uncontaminated material may be mixed according to product directions,
allowed to cure, and disposed of in landfill if local regulations permit.
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| TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Resin Solution U.N. No. 1866
DOT TECHNICAL NAME: Resin Solution
DOT HAZARD CLASS: N/A HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: N/A PACKING GROUP: N/A RESP. GUIDE PAGE:
INTERNATIONAL SHIPPING NAME: Resin Solution U.N. No. 1866
INTERNATIONAL ID NUMBER: 3.3/1866/III
IMDG CLASS (1Û,2Û): N/A IMDG PAGE NUMBER: 330
IMDG EMS: 3.06 IATA CLASS (1Û,2Û): N/A
POLYOXETANE LTD 11/28/08
MATERIAL SAFETY DATA SHEET Page 06 of 07
Item No.: 35672
ADR ITEM NO.: 3/31C ADR TREMCARD: 3/31C
SUPPLEMENTAL INFORMATION: Not Applicable.
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| SECTION 15 - REGULATORY INFORMATION |
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EEC classification according to EEC-rules:
HAZARD SYMBOL :Xn
RISK PHRASES : R 10 (flammable)
R 36 (irritating to the eyes)
R 37/38 (irritating to respiratory system and skin)
R 42/43 (may cause sensitisation by inhalation or skin contact)
Safety phrases : S7/8 ( keep container tightly closed and dry )
S 23-36/37-45
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
4,4'-diphenylmethanediisocyanate 101-68-8 5.0-10.0
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NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Higher Oligomers Of MDI 39310-05-9
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Higher Oligomers Of MDI 39310-05-9
CALIFORNIA PROPOSITION 65:
WARNING: This product contains no chemical(s) known to the State of
California to cause cancer.
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: D2B
COMPONENT RCRA CLASSIFICATIONS: Not regulated
COMPONENT RCRA CODES: Not Applicable.
POLYOXETANE LTD 11/28/08
MATERIAL SAFETY DATA SHEET Page 07 of 07
Item No.: 35672
CERCLA RQ VALUE (MINIMUM): None known
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: -
REASON FOR REVISION: new format
VOLATILE ORGANIC COMPOUNDS (VOCS): 110 grams/ltr
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Health and Safety Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
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The information contained in this MSDS was obtained from current and reliable sources, however, the
data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy.
Since the conditions or handling, storage and disposal of this product are beyond the control of
POLYOXETANE LTD. POLYOXETANE LTD will not be responsible
for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred,
regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS.
Various government agencies may have specific regulations regarding the transportation, handling,
storage, use, or disposal of this product which may not be covered by this MSDS.
The user is responsible for full compliance.