MSDS_EVERLAST_CAROL_PART

11/28/08 MATERIAL SAFETY DATA SHEET Page 01 of 07 |-------------------------------------------------------| | M A T E R I A L S A F E T Y D A T A S H E E T | |-------------------------------------------------------| |=========================================================================| | SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |=========================================================================| PRODUCT NAME : EVERLAST® C.A.R.O.L. PART A IDENTIFICATION NUMBER: 35671, 35672, 35673 PRODUCT USE/CLASS : Anti Rust Primer MANUFACTURER: MADE IN EU by POLYOXETANE LTD London W2 2AP, United Kingdom EU and WORLDWIDE 24 hr emergency contact : Paul Bruns GmbH, Hamburg Germany Phone +49 40 54 77 850 Fax +49 40 54 77 8520 PREPARER: Safety Health & Regulatory Affairs PREPARE DATE: 11/28/08 2009 |=========================================================================| | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |=========================================================================| WT/WT % ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN --------------------------------------------------------------------------- 01 2-Methy-1-Propyl 2-Methylpropanoate 97-85-8 15.0 02 White Spirit,aromatic free 64742-48-9 3.0-5.0 03 Polyoxetane Polymer -- 45.0-65.0 ---------------------- EXPOSURE LIMITS -------------------- ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN --------------------------------------------------------------------------- 01 40 mg/m3 800 mg/m3 60 mg/m3 N/E N.E. NO 02 100 ml/m3 100 ml/m3 150 ml/m3. N/E N.E. NO 03 N.E. N.E. N.E. N/E N.E. NO (See Section 16 for abbreviation legend) |=========================================================================| | SECTION 3 - HAZARDS IDENTIFICATION | |=========================================================================| EMERGENCY OVERVIEW: This health hazard information is based on information on similar products. Low toxicity under normal conditions of handling and use. POLYOXETANE LTD 11/28/08 MATERIAL SAFETY DATA SHEET Page 02 of 07 Item No.: 35671 ACUTE EFFECTS - EYE CONTACT: Contact may cause injury to eye tissue if not removed promptly. =========================================================================== |=========================================================================| | SECTION 3 - HAZARDS IDENTIFICATION | |=========================================================================| ACUTE EFFECTS - SKIN CONTACT: . Prolonged skin contact may cause dermatitis. ACUTE EFFECTS - INHALATION: Vapors and/or aerosols which may be formed at elevated temperatures may be irritating. ACUTE EFFECTS - INGESTION:Ingestion may cause fatigue, muscular weakness, labored breathing. Ingestion of significant amounts may cause kidney damage. CHRONIC OVEREXPOSURE EFFECTS: N.A. OTHER INFORMATION: HMSIS Hazard Ratings: Health-1,Flammability-1, Chemical Reaktivity-0 NFPA Hazard Ratings : Health-1,Flammability-1, Instability-0 PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT |=========================================================================| | SECTION 4 - FIRST AID MEASURES | |=========================================================================| EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Remove contaminated clothing. Wash skin with soap and water. Get medical attention if symptons occur. INHALATION: If symptoms occur, remove to fresh air. Medical personnel may administer oxygen if breathing is difficult. Seek medical attention if symptoms persist. INGESTION: Swallowing less than an ounce will not cause significant harm. POLYOXETANE LTD 11/28/08 MATERIAL SAFETY DATA SHEET Page 03 of 07 Item No.: 35671 =========================================================================== |=========================================================================| | SECTION 5 - FIRE FIGHTING MEASURES | |=========================================================================| FLASH POINT: 48 Celsius 118 F LOWER EXPLOSIVE LIMIT: 0.8 Vol% (PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: 6.8 Vol% AUTOIGNITION TEMPERATURE: 410 Celsius 770 F EXTINGUISHING MEDIA: USE DRY MATERIALS(EX.:SAND) OR CLASS D EXSTINGUISHING AGENT SPECIAL FIREFIGHTING PROCEDURES: Use NIOSH-approved self-contained breathing apparatus and full protective clothing. Use water to cool exposed containers. Water stream directed into fire may cause frothing with subsequent spread of flame. |=========================================================================| | SECTION 6 - ACCIDENTAL RELEASE MEASURES | |=========================================================================| STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Collect large spills mechanically or with liuid absorb material and transfer waste to a leakproof container.Remove all sources of ignition. Don´t use a vakuum cleaner. |=========================================================================| | SECTION 7 - HANDLING AND STORAGE | |=========================================================================| HANDLING: Follow all MSDS/label precautions even after container is emptied because it may retain product residues. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP OUT OF THE REACH OF CHILDREN. POLYOXETANE LTD 11/28/08 MATERIAL SAFETY DATA SHEET Page 04 of 07 Item No.: 35671 |=========================================================================| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |=========================================================================| ENGINEERING CONTROLS: General ventilation usually adequate. Local exhaust as needed to control vapor or dust levels to below lowest component TLV. RESPIRATORY PROTECTION: None normally required under general ventilation. If TLV/PEL is exceeded, if use is performed in a poorly-ventilated space, or if inhalation effects occur, use NIOSH-approved vapor cartridge =========================================================================== |=========================================================================| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |=========================================================================| respirator in accordance with applicable health and safety regulations and manufacturer's recommendations. SKIN PROTECTION: Clean clothing to cover skin. Saranex gloves. Butyl rubber gloves. Neoprene gloves. Nitrile gloves. PVA gloves. EYE PROTECTION: Chemical splash goggles. OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower. HYGIENIC PRACTICES: Follow good general industrial safety practices during use. Do not smoke or eat during use. DO NOT reuse empty containers without commercial clean or recondition. Follow all MSDS/label precautions even after container is emptied. |=========================================================================| | SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |=========================================================================| BOILING RANGE : (300F)150Celsius VAPOR DENSITY : Is heavier than air ODOR : Mild ester ODOR THRESHOLD : No data APPEARANCE : metallic grey EVAPORATION RATE: Is slower than Butyl SOLUBILITY IN H2O : Negligible Acetate FREEZE POINT : No data SPECIFIC GRAVITY: 1.260 VAPOR PRESSURE : No data pH @ 0.0 % : N/A PHYSICAL STATE : Liquid VISCOSITY : medium COEFFICIENT OF WATER/OIL DISTRIBUTION: No data (See Section 16 for abbreviation legend) |=========================================================================| | SECTION 10 - STABILITY AND REACTIVITY | |=========================================================================| CONDITIONS TO AVOID: Keep away from strong oxidizing agents. INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants. POLYOXETANE LTD 11/28/08 MATERIAL SAFETY DATA SHEET Page 05 of 07 Item No.: 35671 HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Various hydrocarbons. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. |=========================================================================| | SECTION 11 - TOXICOLOGICAL PROPERTIES | |=========================================================================| COMPONENT TOXICOLOGICAL INFORMATION: ----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------ MethylPropylMethylpropanoate Oral-rat 30.0 g/kg 40 g/kg (Mouse) White Spirit derm(rbt)9000mg/kg No deaths satd air Polyoxetane Polymer Not Applicable Not Applicable This health hazard assessment is based on information available on similar products. =========================================================================== |=========================================================================| | SECTION 12 - ECOLOGICAL INFORMATION | |=========================================================================| ECOLOGICAL TEST DATA: Not Applicable. The product is essentially insoluble in water. WGK 2 (self classification) The product is anticipated to be partially removed in biological treatment processes. |=========================================================================| | SECTION 13 - DISPOSAL CONSIDERATIONS | |=========================================================================| DISPOSAL METHOD:dispose material in accordance with local, state and federal regulations. |=========================================================================| | TRANSPORTATION INFORMATION | |=========================================================================| DOT PROPER SHIPPING NAME: Coating Solution U.N. No. 1139 DOT TECHNICAL NAME: Coating Solution DOT HAZARD CLASS: N/A HAZARD SUBCLASS: NA DOT UN/NA NUMBER: N/A PACKING GROUP: N/A RESP. GUIDE PAGE: INTERNATIONAL SHIPPING NAME: Coating Solution U.N. No. 1139 INTERNATIONAL ID NUMBER: 3.3/1139/III IMDG CLASS (1Û,2Û): N/A IMDG PAGE NUMBER: 330 IMDG EMS: 3.06 IATA CLASS (1Û,2Û): N/A POLYOXETANE LTD 11/28/08 MATERIAL SAFETY DATA SHEET Page 06 of 07 Item No.: 35672 ADR ITEM NO.: 3/31C ADR TREMCARD: 3/31C SUPPLEMENTAL INFORMATION: Not Applicable. |=========================================================================| | SECTION 15 - REGULATORY INFORMATION | |=========================================================================| EEC classification according to EEC-rules: HAZARD SYMBOL :- RISK PHRASES : R 10 (flammable) Safety phrases : S7/8 ( keep container tightly closed and dry ) S 43 ( in case of fire, use dry sand , never use water ) CALIFORNIA PROPOSITION 65: WARNING: This product contains no chemical(s) known to the State of California to cause cancer. CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. COMPONENT RCRA CLASSIFICATIONS: Not regulated COMPONENT RCRA CODES: Not Applicable. POLYOXETANE LTD 11/28/08 MATERIAL SAFETY DATA SHEET Page 07 of 07 Item No.: 35672 CERCLA RQ VALUE (MINIMUM): None known |=========================================================================| | SECTION 16 - OTHER INFORMATION | |=========================================================================| HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: - REASON FOR REVISION: new format VOLATILE ORGANIC COMPOUNDS (VOCS): 180 grams/ltr LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial Hygienists; OSHA = US Occupational Health and Safety Administration; UK = United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8 hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL = Permissible Exposure Limit ===========================================================================

The information contained in this MSDS was obtained from current and reliable sources, however, the
data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy.
Since the conditions or handling, storage and disposal of this product are beyond the control of
POLYOXETANE LTD. POLYOXETANE LTD will not be responsible
for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred,
regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS.
Various government agencies may have specific regulations regarding the transportation, handling,
storage, use, or disposal of this product which may not be covered by this MSDS.
The user is responsible for full compliance.